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Elastocaloric polymers, whose performance typically relies on phase transformation between amorphous chains and crystalline domains, offer a promising alternative to traditional refrigeration technologies. While engineering polymer‐network architecture has shown the potential to boost elastocaloric performance, the role of topological defects remains unexplored despite their prevalence in real polymers. This study reports a defect‐engineering approach in end‐linked star polymers (ELSPs) that enables an adiabatic temperature change of up to 8.14 ± 1.76 °C at an ambient temperature above 65 °C, showing an enhancement of 39% compared to ELSPs with negligible defects. This defect‐regulated solid‐state cooling is attributed to two competing effects of dangling‐chain defects on strain‐induced crystallization (SIC) and temperature‐induced crystallization (TIC), synergistically regulating the adiabatic temperature change. Specifically, increasing dangling‐chain defects monotonically lowers ELSPs’ mechanical performance at high temperatures due to suppressed SIC, but nonmonotonically impacts the mechanical performance at low temperatures due to the competition between suppressed SIC and enhanced TIC. 

Abstract Recent studies have suggested a correct representation of cloud phase in the Southern Ocean region is important in climate models for an accurate representation of the energy balance. Satellite retrievals indicate many of the clouds are predominantly liquid, despite their low temperatures. However, clouds containing high numbers of ice crystals have sometimes been observed in this region and implicated the secondary ice production process called rime splintering. This study re‐examines rime splintering in Southern Ocean cumuli using both a new data set and high‐resolution numerical modeling. Measurements acquired during the Southern Ocean Clouds Radiation Aerosol Transport Experimental Study (SOCRATES) provide an evaluation of the amount of ice in shallow cumuli sampled over two days in this region. The measurements sometimes exhibit seven orders of magnitude or more ice particles compared to amounts expected from measurements of ice‐nucleating particles (INP) on the same days. Cumuli containing multiple updrafts had the greatest tendency to contain high ice concentrations and meet the expected conditions for rime splintering. Idealized numerical modeling, constrained by the observations, suggests that the multiple updrafts produce more frozen raindrops/graupel, and allow them to travel through the rime‐splintering zone over an extended period of time, increasing the number of ice particles by many orders of magnitude. The extremely low number of INP in the Southern Ocean thus appears to require special conditions like multiple updrafts to help glaciate the cumuli in this region, potentially explaining the predominance of supercooled cumuli observed there.